AQA GCSE Chemistry · 4.1

Atomic structure and the periodic table

50 exam-style questions with answers for 4.1 Atomic structure and the periodic table in AQA GCSE Chemistry (spec 8462). Practise with flashcards, a topic quiz, a random quiz across the course, 5 crosswords, or read every question and answer below. Not official AQA material.

All 50 questions and answers

  1. Question 1 · Spec 4.1.1.1 · Atoms and elements

    What is an element? [1 mark]

    Answer:
    A substance made of only one sort of atom.
  2. Question 2 · Spec 4.1.1.1 · Compounds

    What is a compound? [2 marks]

    Answer:
    Two or more elements chemically combined (1); in fixed proportions (1).
  3. Question 3 · Spec 4.1.1.1 · Equations

    Balance the equation: Mg + O₂ → MgO. [1 mark]

    Answer:
    2Mg + O₂ → 2MgO.
  4. Question 4 · Spec 4.1.1.1 · Compounds

    Why can compounds only be separated by chemical reactions? [1 mark]

    Answer:
    The elements are chemically bonded together.
  5. Question 5 · Spec 4.1.1.2 · Mixtures

    What is a mixture? [1 mark]

    Answer:
    Two or more elements or compounds not chemically combined together.
  6. Question 6 · Spec 4.1.1.2 · Separation

    Name four physical processes used to separate mixtures. [2 marks]

    Answer:
    Filtration and crystallisation (1); simple distillation, fractional distillation or chromatography (1).
  7. Question 7 · Spec 4.1.1.2 · Separation

    Describe how to obtain pure salt crystals from rock salt. [3 marks]

    Answer:
    Dissolve the rock salt in warm water (1); filter to remove the insoluble sand (1); evaporate some of the water and leave to crystallise (1).
  8. Question 8 · Spec 4.1.1.2 · Distillation

    What is simple distillation used for? [1 mark]

    Answer:
    To separate a liquid from a solution, for example water from salty water.
  9. Question 9 · Spec 4.1.1.3 · Atomic model

    Describe the plum pudding model. [2 marks]

    Answer:
    A ball of positive charge (1); with negative electrons embedded in it (1).
  10. Question 10 · Spec 4.1.1.3 · Atomic model

    What did the alpha scattering experiment show? [2 marks]

    Answer:
    The mass of an atom is concentrated at the centre (nucleus) (1); and the nucleus is charged (positive) (1).
  11. Question 11 · Spec 4.1.1.3 · Atomic model

    What did James Chadwick show? [1 mark]

    Answer:
    The existence of neutrons in the nucleus.
  12. Question 12 · Spec 4.1.1.4 · Subatomic particles

    State the relative charges of protons, neutrons and electrons. [2 marks]

    Answer:
    Proton +1 and electron −1 (1); neutron 0 (1).
  13. Question 13 · Spec 4.1.1.4 · Subatomic particles

    Why do atoms have no overall charge? [1 mark]

    Answer:
    They have equal numbers of protons and electrons.
  14. Question 14 · Spec 4.1.1.5 · Atomic size

    What is the approximate radius of an atom? [1 mark]

    Answer:
    0.1 nm (1 × 10⁻¹⁰ m).
  15. Question 15 · Spec 4.1.1.5 · Atomic mass

    State the relative masses of a proton, neutron and electron. [2 marks]

    Answer:
    Proton and neutron: 1 (1); electron: very small (about 1/1840) (1).
  16. Question 16 · Spec 4.1.1.5 · Atomic number

    How many neutrons are in an atom of ³⁵Cl (atomic number 17)? [1 mark]

    Answer:
    35 − 17 = 18.
  17. Question 17 · Spec 4.1.1.5 · Isotopes

    What are isotopes? [2 marks]

    Answer:
    Atoms of the same element with the same number of protons (1); but different numbers of neutrons (1).
  18. Question 18 · Spec 4.1.1.6 · Relative atomic mass

    Chlorine is 75% ³⁵Cl and 25% ³⁷Cl. Calculate its relative atomic mass. [2 marks]

    Answer:
    (35 × 75 + 37 × 25) ÷ 100 (1); = 35.5 (1).
  19. Question 19 · Spec 4.1.1.7 · Electronic structure

    Write the electronic structure of sodium (atomic number 11). [1 mark]

    Answer:
    2,8,1.
  20. Question 20 · Spec 4.1.1.7 · Electronic structure

    Write the electronic structure of chlorine (atomic number 17). [1 mark]

    Answer:
    2,8,7.
  21. Question 21 · Spec 4.1.2.1 · Periodic table

    How are elements arranged in the modern periodic table? [1 mark]

    Answer:
    In order of atomic (proton) number.
  22. Question 22 · Spec 4.1.2.1 · Periodic table

    Why do elements in the same group have similar chemical properties? [1 mark]

    Answer:
    They have the same number of electrons in their outer shell.
  23. Question 23 · Spec 4.1.2.2 · Mendeleev

    State two things Mendeleev did when arranging his periodic table. [2 marks]

    Answer:
    Left gaps for elements he thought had not been discovered (1); changed the order of some elements based on atomic weights to fit patterns in properties (1).
  24. Question 24 · Spec 4.1.2.2 · Mendeleev

    Why was Mendeleev's table accepted? [1 mark]

    Answer:
    Elements were later discovered that fitted the gaps and matched his predictions.
  25. Question 25 · Spec 4.1.2.2 · Isotopes

    Why did isotopes explain why ordering by atomic weight was not always correct? [1 mark]

    Answer:
    Isotopes of an element have different masses but the same atomic number, so atomic number is the right order.
  26. Question 26 · Spec 4.1.2.3 · Metals

    Where are metals found in the periodic table? [1 mark]

    Answer:
    To the left and towards the bottom.
  27. Question 27 · Spec 4.1.2.3 · Metals

    Why do metals form positive ions? [1 mark]

    Answer:
    They lose electrons from their outer shell.
  28. Question 28 · Spec 4.1.2.4 · Group 0

    Why are the noble gases unreactive? [2 marks]

    Answer:
    They have stable arrangements of electrons (1); a full outer shell (eight, or two for helium), so they do not easily gain or lose electrons (1).
  29. Question 29 · Spec 4.1.2.4 · Group 0

    How do the boiling points of noble gases change down the group? [1 mark]

    Answer:
    They increase with increasing relative atomic mass.
  30. Question 30 · Spec 4.1.2.5 · Group 1

    Describe the reaction of sodium with water. [2 marks]

    Answer:
    It fizzes, floats and moves around, melting into a ball (1); producing sodium hydroxide and hydrogen (1).
  31. Question 31 · Spec 4.1.2.5 · Group 1

    Write the word equation for lithium reacting with water. [1 mark]

    Answer:
    Lithium + water → lithium hydroxide + hydrogen.
  32. Question 32 · Spec 4.1.2.5 · Group 1

    Explain why reactivity increases down Group 1. [3 marks]

    Answer:
    The outer electron is further from the nucleus (1); there is more shielding by inner shells (1); so the outer electron is lost more easily (1).
  33. Question 33 · Spec 4.1.2.5 · Group 1

    Write the formula of the compound formed between potassium and chlorine. [1 mark]

    Answer:
    KCl.
  34. Question 34 · Spec 4.1.2.6 · Group 7

    Describe how the melting and boiling points of halogens change down the group. [1 mark]

    Answer:
    They increase as relative molecular mass increases.
  35. Question 35 · Spec 4.1.2.6 · Group 7

    Explain why reactivity decreases down Group 7. [3 marks]

    Answer:
    The outer shell is further from the nucleus (1); more shielding (1); so it is harder to gain an electron (1).
  36. Question 36 · Spec 4.1.2.6 · Displacement

    What is seen when chlorine water is added to potassium bromide solution? [2 marks]

    Answer:
    The solution turns orange (1); because chlorine is more reactive and displaces bromine (1).
  37. Question 37 · Spec 4.1.2.6 · Group 7

    Describe chlorine at room temperature. [1 mark]

    Answer:
    A green gas.
  38. Question 38 · Spec 4.1.2.6 · Displacement

    Write a word equation for chlorine displacing iodine from sodium iodide. [1 mark]

    Answer:
    Chlorine + sodium iodide → sodium chloride + iodine.
  39. Question 39 · Spec 4.1.3.1 · Transition metals

    State two ways transition metals differ from Group 1 metals. [2 marks]

    Answer:
    Any two from: higher melting points (except mercury) (1); higher densities (1); stronger and harder (1); much less reactive with water and oxygen (1).
  40. Question 40 · Spec 4.1.3.2 · Transition metals

    State two typical properties of transition metal compounds. [2 marks]

    Answer:
    Many form coloured compounds (1); many are useful as catalysts (1).
  41. Question 41 · Spec 4.1.3.2 · Transition metals

    Why can transition metals form ions with different charges? [1 mark]

    Answer:
    They can lose different numbers of electrons, for example Fe²⁺ and Fe³⁺.
  42. Question 42 · Spec 4.1.3.2 · Catalysts

    Give one example of a transition metal used as a catalyst. [1 mark]

    Answer:
    Iron in the Haber process (or nickel in the hydrogenation of oils).
  43. Question 43 · Spec 4.1.1.2 · Chromatography

    What is chromatography used for? [1 mark]

    Answer:
    To separate mixtures of soluble substances, such as dyes in an ink.
  44. Question 44 · Spec 4.1.1.2 · Fractional distillation

    What is fractional distillation used for? [1 mark]

    Answer:
    To separate a mixture of liquids with different boiling points.
  45. Question 45 · Spec 4.1.1.7 · Electronic structure

    Describe the maximum number of electrons in the first three shells. [1 mark]

    Answer:
    2, 8 and 8.
  46. Question 46 · Spec 4.1.2.1 · Periodic table

    What does the period number tell you about an element's electrons? [1 mark]

    Answer:
    The number of occupied electron shells.
  47. Question 47 · Spec 4.1.2.3 · Non-metals

    Do non-metals form positive or negative ions? [1 mark]

    Answer:
    Negative ions, by gaining electrons.
  48. Question 48 · Spec 4.1.1.1 · Symbols

    How many atoms are in one molecule of H₂SO₄? [1 mark]

    Answer:
    7 (2 H, 1 S, 4 O).
  49. Question 49 · Spec 4.1.2.5 · Group 1

    Why are Group 1 metals stored in oil? [1 mark]

    Answer:
    To stop them reacting with oxygen and water in the air.
  50. Question 50 · Spec 4.1.2.6 · Group 7

    Why do halogens exist as diatomic molecules? [1 mark]

    Answer:
    Two atoms share a pair of electrons to form a covalent bond, giving each a full outer shell.

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